بررسی میزان جذب یک سرفکتانت پلیمری برروی سنگ مخزن در شرایط مختلف و مقایسه آن با HPAM

نوع مقاله : مقاله پژوهشی

نویسندگان

1 'گروه مهندسی نفت، واحد امیدیه، دانشگاه آزاد اسلامی، امیدیه، ایران

2 انستیتو مهندسی نفت، دانشکده مهندسی شیمی، دانشکدگان فنی، دانشگاه تهران، ایران

چکیده

هدر رفتن سرفکتانت و پلیمر در طی عملیات تزریق در مخازن به‌عنوان مهم‌ترین مسأله در امکان‌پذیر بودن عملیات تزریق مواد شیمیایی محسوب می‌گردد. تزریق هم‌زمان پلیمر و سرفکتانت نیز باعث ایجاد برهم‌کنش بین سرفکتانت و پلیمر شده و سبب کاهش قابل‌ملاحظه‌ای در عملکرد آن‌ها می‌گردد. بهترین راه‌حل برای برطرف نمودن این مشکل استفاده از ماده‌ای جدید به نام سرفکتانت پلیمری است که می‌تواند یک جایگزین بسیار جذاب برای استفاده هم‌زمان این دو ماده تلقی گردد. یکی از مشکلات اساسی تزریق مواد شیمیایی، جذب این مواد برروی سنگ مخزن است که به‌دلیل آن که پژوهش ها محدودی در رابطه با بررسی میزان جذب سرفکتانت پلیمری برروی سنگ مخازن و مقایسه آن با میزان جذب پلیمرهای معمولی انجام شده است، در این پژوهش میزان جذب یک سرفکتانت پلیمری و یک پلیمر معمولی در دماهای مختلف برروی نمونه سنگ کربناته مورد بررسی قرار گرفته است. ابتدا پلی‌اکریل‌آمید هیدرولیز شده (HPAM) و پلی‌اکریل‌آمید اصلاح شده آبگریز (HMZPAM)، به‌عنوان یک سرفکتانت پلیمری، با استفاده از یک گروه آب‌گریز زویتری سنتز گردید و در ادامه اثر این دو پلیمر در غلظت‌های 50 تا mg/L 1000 در دمای 25 تا C° 80، برروی جذب سطحی در سنگ کربناته بررسی شد. نتایج کلی حاصل از این آزمایش‌ها نشان می‌دهد که جذب سطحی HPAM و HMZPAM برروی سنگ مخزنی از جنس دولومیت (دارای بار سطحی مثبت)، با افزایش غلظت پلیمر، افزایش می‌یابد. به‌طورکلی می‌توان گفت که عامل اصلی در جذب سطحی پلیمرها، نیروهای الکترواستاتیکی می‌باشند که به‌دلیل آن که پلیمر HMZPAM نسبت به پلیمر HPAM، در ساختار خود علاوه بر گروه‌ عاملی منفی -COO، گروه عاملی منفی SO3- را نیز دارد، این گروه‌های عاملی منفی، بیشتر جذب بار مثبت سطح سنگ شده که در نتیجه سبب افزایش میزان جذب سرفکتانت پلیمری HMZPAM نسبت به HPAM می‌گردند.
 

کلیدواژه‌ها


عنوان مقاله [English]

Evaluation of Adsorption of a Polymeric Surfactant on Reservoir Rock in Different Conditions and its Comparison with HPAM

نویسندگان [English]

  • Elias Ghaleh Golab 1
  • Siavash Riahi 2
1 Department of Petroleum Engineering, Omidiyeh Branch, Islamic Azad University, Omidiyeh, Iran
2 Institute of Petroleum Engineering, School of Chemical Engineering, College of Engineering, University of Tehran, Tehran, Iran
چکیده [English]

The loss of surfactants and polymers in the injection process in reservoirs is considered the most crucial issue in the chemical injection process›s Feasibility. Simultaneous injection of polymers and surfactants causes interaction between surfactant and polymer and a significant reduction in performance. The best solution for solving this problem is using a new material called polymeric surfactant that can be an exciting alternative for currently available methods. These new materials can have the effect of polymer and surfactant like increase of water viscosity, reduction of interfacial tension between water and oil, and change in reservoir rock wettability simultaneously; thus, these new materials will further increase oil production relative to traditional methods. One of the fundamental problems of chemical injection is the adsorption of these substances on the reservoir rock. Because of limited research regarding the analysis of the adsorption rate of polymeric surfactant on reservoir rocks and comparing them with the adsorption rate of conventional polymers, in this study, the adsorption rate of this substance has been studied in different temperatures. First, in this research, A HPAM and HMZPAM As a polymeric surfactant synthesized using a Zwitterion hydrophobic group, and the effect of these two polymers was measured in concentrations between 50 to 1000 mg/L at temperatures between 25 to 80 oC on adsorption of surface in carbonate rock. The results show that the adsorption of HPAM and HMZPAM on reservoir rock, which made of dolomite, increases with the increase in polymer›s concentration. Generally, the main factor in the adsorption of polymers are electrostatic forces which because HMZPAM compared to HPAM, in addition to COO- group also has SO3- group that these negative groups adsorbed more to the positive charge of the rock surface in which as a result increases the amount of adsorption of polymeric surfactant compared to HPAM.
 
 

کلیدواژه‌ها [English]

  • Polymeric Surfactant
  • Polymer
  • Adsorption
  • Temperature
  • Dolomite
 
[1]. Thomas S (2008) Enhanced oil recovery - an overview, Oil Gas Oil and Gas Science and Technology - Rev. IFP, 6: 9-19.
[2]. Alvarado V, Manrique E (2010) Enhanced oil recovery: an update review, Energies, 3: 1529-1575. ##
[3]. Zhao T H, Xing J Y, Dong Z M, Tang Y L, Pu W F (2015) Synthesis of polyacrylamide with superb salt-thickening performance, Ndustrial and Engineering Chemistry Research, 54: 10568−10574. ##
[4]. Gou S, Ye Z, Chang J, Gou G, Feng M (2011) Modular amino acid amide chiral ligands for enantioselective addition of diethylzinc to aromatic aldehydes, Applied Organometallic Chemistry, 25: 448-453. ##
[5]. Fava A, Eyring H (1956) Equilibrium and kinetics of detergent adsorption—a generalized equilibration theory, The Journal of Physical Chemistry, 60, 7: 890‐898. ##
[6]. Al-Wahabi Y, Al-Hashemi A Z, Joshi S, Mosavat N, Rudyk S, Al-khamisi S, al-kharusi T, al-Sulaimani H (2017) Mechanistic study of surfactant/polymer adsorption and its effect on surface morphology and wettability, SPE-185327-MS. ##
[7]. Olajire A A (2014) Review of ASP EOR (alkaline surfactant polymer enhanced oil recovery) technology in the petroleum industry: Prospects and challenges, Energy, 77: 963-982. ##
[8]. Al-Hajri S, Mahmood S M, Akbari S, Abdulelah H, Yekeen N, Saraih N (2020) Experimental investigation and development of correlation for static and dynamic polymer adsorption in porous media, Journal of Petroleum Science and Engineering, 189. ##
[9]. Sazali R A, Roslan M S, Jarrahian K (2019) Adsorption study of acrylamide-tertiary-butyl sulfonate (ATBS)/ acrylamide copolymer in polymer flooding enhanced    oil recovery (EOR) process, Journal of Physics: Conference Series, 1349. ##      
[10]. Golabi4 E, Seyedeyn-Azad F, Ayatollahi Sh (2009) Chemical induced wettability alteration of carbonate reservoir rock, Iranian Journal of Chemical Engineering, 6, 1: 66-73. ##
[11]. Golabi E, Seyedeyn-Azad F, Ayatollahi Sh, Hoseini N, Akhlaghi N (2012) Experimental study of wettability alteration of limestone rock from oil-wet to water-wet using various surfactants, this paper was prepared for presentation at the SPE Heavy Oil Conference Canada held in Calgary, Alberta, Canada, 12–14 June. ##
[12]. Al-Sabagh A M (2000) Surface activity and thermodynamic properties of water-soluble polyester surfactants based on 1, 3-dicarboxymethoxybenzene used for enhanced oil recovery, Polymers for Advanced Technologies, 11: 48-56. ##
[13]. Al-Murayri M T, Al-Mayyan H E, Al-Mahmeed N (2019) Alkali-Surfactant adsorption and polymer injectivity measurements using reservoir core from a giant high temperature and high salinity clastic reservoir to design an ASP pilot, In SPE Kuwait Oil and Gas Show and Conference. OnePetro. ##
[14]. Busse K, Kressler J, van Eck D, Horing S (2002) Synthesis of amphiphilic block copolymers based on tert-butyl methacrylate and 2-(N-methylperfluorobutanesulfonamido) ethyl methacrylate and its behavior in water, Macromolecules, 35: 178-184. ##
[15]. Desbrieres J, Babak V (2010) Interfacial properties of chitin and chitosan-based systems, Soft Matter, 6: 2358-2363. ##
[16]. Sun J, Xu X, Wang J, Zhang W, Yang H, Jing X, Shi X (2010) Synthesis and Emulsification Properties of an Amphiphilic Polymer for Enhanced Oil Recovery, Ournal of Dispersion Science and Technology, 31: 931-935. ##
[17]. Elraies K A, Tan I M, Fathaddin M T, Abo-Jabal A (2011) Development of a new polymeric surfactant for chemical enhanced oil recovery, Petroleum Science and Technology, 29: 1521-1528. ##
[18]. Fischer A, Brembilla A, Lochon P (2001) Synthesis of new amphiphilic cationic block copolymers and study of their behaviour in aqueous medium as regards hydrophobic microdomain formation, Polymer, 42: 1441-1448. ##
[19]. Raffa P, Wever D A Z, Picchioni F, Broekhuis A A (2015) Polymeric surfactants: synthesis, properties, and links to applications,Chemical Reviews, 115: 8504-8563. ##
[20]. Ezell R G, McCormick C L (2007) Electrolyte- and pH-responsive polyampholytes with potential as viscosity-control agents in enhanced petroleum recovery, Journal of Applied Polymer Science, 104: 2812, 2721. ##
[21]. Shashkina YA, Zaroslov Y D, Smirnov V A, Philippova O E, Khokhlov A R, Pryakhina T A, Churochkina N A (2003) Hydrophobic aggregation in aqueous solutions of hydrophobically modified polyacrylamide in the vicinity of overlap concentration, Polymer, 44: 2289-2293. ##
[22]. Ahmadi M A, Shadizadeh S R (2013) Induced effect of adding nano silica on adsorption of a natural surfactant onto sandstone rock: experimental and theoretical study, Journal of Petroleum Science and Engineering, 112:239‐247. ##
[23]. Scamehorn J F, Schechter R S, Wade W H (1982) Adsorption of surfactants on mineral oxide surfaces from aqueous solutions, Journal of Colloid and Interface Science, 85, 2:463‐478. ##
[24]. Bera A, Kissmathulla S, Ojha K, Kumar T, Mandal A (2012) Mechanistic study of wettability alteration of quartz surface induced by nonionic surfactants and interaction between crude oil and quartz in the presence of sodium chloride salt, Energy Fuel, 26, 6:3634‐3643. ##
[25]. Zhu L, Yang K, Lou B, Yuan B A (2003) Multi‐component statistical analysis for the influence of sediment/soil composition on the sorption of a nonionic surfactant (Triton X‐100) onto natural sediments/soils, Water Res, 37, 19: 4792‐4800. ##
[26]. Somasundaran P, Krishnakumar S (1997) Adsorption of surfactants and polymers at the solid‐liquid interface, Colloids Surf A, Colloids and Surfaces A: physicochemical and engineering aspects, 123‐124:491‐513. ##
[27]. Drach M, Jabłoński J, Narkiewicz‐Michałek J, Szymula M (2010) Coadsorption of surfactants and propyl gallate on the hydrophilic oxide surfaces, Applied Surface Science, 256, 17: 5444‐5448. ##
[28]. Somasundaran P, Fuerstenau D W (1966) Mechanisms of alkyl sulfonate adsorption at the alumina‐water interface1, The Journal of Physical Chemistry, 70, 1: 90‐96. ##
[29]. Yeskie M A, Harwell J H (1988) On the structure of aggregates of adsorbed surfactants: the surface charge density at the hemimicelle/admicelle transition, The Journal of Physical Chemistry, 92, 8: 2346‐2352. ##
[30]. Zhang R, Somasundaran P (2006) Advances in adsorption of surfactants and their mixtures at solid/solution interfaces, Advances in Colloid and Interface science, 123:213‐229. ##
[31]. Esmaeilzadeh P, Bahramian A, Fakhroueian Z (2011) Adsorption of anionic, cationic and nonionic surfactants on carbonate rock in presence of ZrO2 nanoparticles, Physics Procedia, 22: 63‐67. ##
[32]. Shamsijazeyi H, Hirasaki G, Verduzco R (2013) Sacrificial agent for reducing adsorption of anionic surfactants, In SPE International Symposium on Oilfield Chemistry Society of Petroleum Engineers. ##
[33]. الیاس قلعه گلاب، سیاوش ریاحی، محمد وطن‌خواه ورنوسفادرانی، علی نخعی. سنتز، معرفی و مطالعه خواص رئولوژیکی یک سرفکتانت پلیمری جدید و بررسی اثر آن بر کشش بین‌سطحی آب و نفت در شوری‌های متفاوت. مجله پژوهش نفت، دوره دوم 98. ##
[34]. Hou B F, Wang Y F, Huang Y (2015) Mechanistic study of wettability alteration of oil‐wet sandstone surface using different surfactants, Applied Surface Science, 330:56‐64. ##
[35]. Saxena N, Kumar S, Mandal A (2018) Adsorption characteristics and kinetics of synthesized anionic surfactant and polymeric surfactant on sand surface for application in enhanced oil recovery, sia‐Pacific Journal of Chemical Engineering, e2211. ##
[36]. Ziegler V M, Handy L L (1981) Effect of temperature on surfactant adsorption in porous media, Society of Petroleum Engineers Journal, 218-228. ##
[37]. Azam M R, Tan I M, Ismail L, Mushtaq M (2013) Static adsorption of anionic surfactant onto crushed Berea sandstone, Journal of Petroleum Exploration and Production Technology, 3: 195–201. ##
[38]. Paria S, Khilar K C (2004) A review on experimental studies of surfactant adsorption at the hydrophilic solid–water interface, Advances in Colloid and Interface Science, 110: 75– 95. ##
[39]. Corkill J M, Goodman J F, Tate J R (1966) Adsorption of non‐ionic surface‐active agents at the graphon/solution interface, Transactions of the Faraday Society, 62: 979‐986. ##
[40]. Curbelo F D, Santanna V C, Neto E L B, Dutra J r, T V, Dantas T N C, Neto A A D, Garnica A I (2007) Adsorption of nonionic surfactants in sandstones, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 293, 1-3: 1-4. ##
[41]. Liu J, Y.Guo Hu J, Zhang J, Lv X, Zhang X, Xue X, Luo P (2012) Displacement characters of combination flooding systems consisting of gemini-nonionic mixed surfactant and hydrophobically associating polyacrylamide for bohai offshore oilfield, Energy Fuels, 26: 2858−2864. ##